In my opinion-there are at least two things that a match chamber gives you that you don't get in a "sporting" chamber.
1. Concentricity; since the bullet is engraved by the rifling, it's centered (concentric) in the bore upon loading. In a sporting chamber, the bullet has to make a jump from the chamber to the rifling and the bullet may be off center in the barrel.
2. Higher pressure and a more complete powder burn: In a sporting chamber, once the bullet crimp (what holds the bullet in the case), is overcome by the powder burn, the pressure within the case begins to drop. In a match chamber, the bullet is held in place in the case by the crimp, but also by its engraving of the rifling. It takes more pressure for the bullet to overcome both of these forces. More pressure and a more complete burn of the powder. Hopefully, you get a lower standard deviation in velocity as well as a higher velocity on a shot-to-shot basis, (however, a higher velocity is not always wanted as it's accompanied by a higher drag coefficient).