It is easy to find what it is and really either problem is easy to fix. I do NOT recommend shimming the scope mount, because you are putting stress on a part that is designed to be bolted flat.
Just take the mount off, wipe it off and hold a straight edge to the top of the receiver. If the hump is there, you will find it. Just FYI for all the press this problem gets here I have never had one.
If it is barrel droop, it is also easy to tell. If the barrel fits loosely into the reciever, it is probably the problem. If you barely tighten the screws and shoot it, then snug them up real good and the POI changes dramatically, that is barrel droop. The soda can strip is a good temporary fix and if you have no intention of taking it apart ever (HAAA ha ha ha!!!) you could make it a permanent solution. Just tear a piece off about 1/2" square (maybe a bit smaller) and fit it between the barrel lug and the receiver extention - NOT into the receiver. This will prop it up some.
Don't over tighten the V/Block screws. What I have found for a permanent solution is the Gunsmither Block. It is not a V/block but a flat block with a small set screw in it. I use one on every 10/22 I have that is a loose fit. It solves the problem and it is a very well designed and made piece.
While you are at it, check and make sure that your action screw is not too long. I check that on every gun now and they usually are. It's a good time to check and be rid of that problem while you are at it. Dakotan sells some first class replacement screws.